When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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| DATAFILE: | C2H5O2_Tyndall(2001)_298K_210-300nm(eval).txt |
| NAME: | ethylperoxy radical |
| FORMULA: | C2H5O2 |
| AUTHOR(YEAR): | Tyndall(2001) |
| T: | 298K |
| λ: | 210-300nm(eval) |
| BIBLIOGRAPHY: |
G.S. Tyndall, R.A. Cox, C. Granier, R. Lesclaux, G.K. Moortgat, M.J. Pilling, A.R. Ravishankara, and T.J. Wallington, "The atmospheric chemistry of small organic peroxy radicals",
J. Geophys. Res. 106(D11), 12157-12182 (2001);
DOI: 10.1029/2000JD900746
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| COMMENTS: | Recommendation based on the data of T.J. Wallington, P. Dagaut, and M.J. Kurylo, "Measurements of the gas phase UV absorption spectrum of C2H5O2 radicals and of the temperature dependence of the rate constant for their self-reaction," J. Photochem. Photobiol. A: Chem. 42, 173-185 (1988), M.M. Maricq and T.J. Wallington, "Absolute ultraviolet cross sections of methyl and ethyl peroxy radicals," J. Phys. Chem. 96, 986-992 (1992), D. Bauer, J.N. Crowley, and G.K. Moortgat, "The UV absorption spectrum of the ethylperoxy radical and its self-reaction kinetics between 218 and 333 K," J. Photochem. Photobiol. A 65, 329-344 (1992), and F.F. Fenter, V. Catoire, R. Lesclaux, and P.D. Lightfoot, "The ethylperoxy radical: Its ultraviolet spectrum, self-reaction, and reaction with HO2, each studied as a function of temperature," J. Phys. Chem. 97, 3530-3538 (1993). The data were fitted to the Sulzer-Wieland function σ = σmax × exp{-a [ln (ν - νmax)]2} which yielded σmax = 4.52×10-18 cm2·molecule-1, λmax = 239.4 nm, and a = 49.0 |
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